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作者曾报道了一些二茂钛二羧酸衍生物的合成及结构,本文选择具有一定空间位阻并具有某些药理作用的羧酸配体进行相应的二茂钛二羧酸配合物的合成,并首次报道该类配合物在活性氢化钠存在下对已烯-1的催化加氢行为。
The authors have reported the synthesis and structure of some titanocene dicarboxylic acid derivatives. In this paper, the synthesis of the corresponding titanocene dicarboxylic acid complexes with carboxylic acid ligands with some steric hindrance and some pharmacological effects were selected. The catalytic hydrogenation of hexene-1 in the presence of sodium hydride was reported for the first time.