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The reaction of 2,6-diformyl-4-methylphenol, ethylenediamine and Cu(Ⅱ) in the proportion of 3:2:2 yields a new tetranuclear copper(II) complex, [Cu2L]2(ClO4)2·2H2O (H3L = N,N′-bis(4-(3′-formyl-5′-methylsalicyclidene)iminoethyl)-4-methyl-2,6-bimethyli