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本文介绍了目前国内外关于镧系配合物４ｆ轨道成键行为研究的现状与进展，对其理论和研究方法进行了系统的总结，归纳了４ｆ轨道的成键规律。
In this paper, the present and future research on the bonding behavior of 4f orbital of lanthanide complexes is introduced. The theory and research methods are systematically summarized, and the bonding rules of 4f orbitals are summarized.