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Two transition metal dinuclear complexes of [Mn2(OOCC6H4SSC6H4COO)-(Phen)2(H2O)]n 1 and [Cu2(OOCC6H4S)2(Phen)2] 2 were hydrothermally synthesized by the reaction of equivalent metal dichloride with 2,2'-dithiobis(benzoic acid) (H2-DTBB). Structure ana