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合成了1,5-二硒杂[5]二茂铁环蕃的铜(Ⅰ)配合物,并用X-射线衍射单晶结构分析确定了其结构。配体的较小环径导致与铜离子配位时必须改变构型。电化学研究表明,由于2个二茂铁基团Fe…Fe的化学键距离为1.269(2)～1.277(3)nm,因此存在强电化学联系。
The copper (Ⅰ) complex of 1,5-diselenazepine [5] ferrocene was synthesized and its structure was confirmed by X-ray diffraction single crystal structure analysis. The smaller ring size of the ligand leads to the need to change conformations when coordinating with copper ions. Electrochemical studies show that there is a strong electrochemical relationship due to the chemical bond distance between two ferrocene groups Fe ... Fe ranging from 1.269 (2) to 1.277 (3) nm.