报导在阳离子表面活性剂溴化十六烷基三甲铵（CTMAB）存在下mcso-四（对-磺基苯基）卟啉（TPPS_4）发生聚集的电子吸收光谱、荧光光谱和共振光散射光谱特性．结果表明：CTMAB低于1．0×10~(－5)mol·L~(-1)时TPPS_4发生J-型聚集，形成一种交错卡迭式二聚体。在1．0×10~(－5)～1.0×10~(－4)mol·L~(－1)时，J-型聚集产物仍然存在，但TPPS_4的Soret蜂蓝移．如果CTMAB浓度高于1．0×10~（-4）mol·L~（-1），J-型聚集产物消失，出现游离碱卟啉的D_(2h)。吸收特征．相对于水介质，游离碱卟啉的Soret带在CTMAB胶束中红移． The electron absorption, fluorescence and resonance light scattering spectra of mcso-tetrakis (p-sulfophenyl) porphyrin (TPPS_4) aggregated in the presence of the cationic surfactant cetyltrimethylammonium bromide (CTMAB) . The results showed that when the CTMAB was lower than 1.0 × 10 -5 mol·L -1, the TPPS_4 aggregated to form a kind of staggered card-type dimers. At 1.0 × 10 -5 to 1.0 × 10 -4 mol·L -1, J-type aggregates still exist, but the Soret of TPPS_4 migrates blue. If the concentration of CTMAB is higher than 1.0 × 10 -4 mol·L -1, the J-type aggregates disappear and the D_ (2h) of free base porphyrin appears. Absorption characteristics. Soret bands of free base porphyrin red-shifted in CTMAB micelles relative to aqueous media.