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本文以6,6-二烷基富烯与甲基锂、芳基锂及烯丙基格氏试剂反应所得的取代环戊二烯基负离子与二茂铁甲酰氯反应合成了10个新的富烯化合物,并通~1H NMR、IR及元素分析确定了它们的结构。
In this paper, six novel dialkylenes have been synthesized by the reaction of 6,6-dialkylfulvene with methyllithium, aryl lithium and allylic Grignard reagent to replace cyclopentadienyl anion with ferrocene chloride Their structures were confirmed by 1H NMR, IR and elemental analysis.