论文部分内容阅读
以γ-[Si W10 O3 6]8-及桥联的 K4 Ru2 OCl10 为原料 ,合成了 (Bu4 N) 7H3 [Ru2 O(H2 O) 2 (γ-Si W10 O3 6) 2 ],经红外光谱、电子光谱、顺磁共振、磁化率、循环伏安和核磁共振等的表征 ,证明标题化合物为两聚夹心结构 .其中 ,γ-[Si W10 O3 6]8-结构保持不变 ,填入的 Ru— O— Ru为直线型 ,均保持了原料的基本构型
(Bu4N) 7H3 [Ru2 O (H2 O) 2 (γ-Si W10 O3 6) 2] was synthesized from γ- [Si W10 O3 6] 8- and bridged K4 Ru2 OCl10. , Electron spectroscopy, paramagnetic resonance, magnetic susceptibility, cyclic voltammetry and nuclear magnetic resonance were used to characterize the title compound as a dimeric sandwich structure in which the structure of γ- [Si W10 O3 6] 8- remained unchanged, Ru-O-Ru is a straight line, maintaining the basic configuration of the raw material