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A novel one-dimensional chain manganese(II) compound Mn(trz)2ClphthH, (trz=1,2,4-triazole, phthH=hydrogen phthalate), 1, was synthesized and structurally characterized. It crystallizes in monoclinic system, space group P2 / c with a=1.381 1(11) nm, b=0.815 5(7) nm, c=0.735 4(6) nm, β=94.667(15)°, V=0.825 5(12) nm3. It consists of one dimensional cationic manganese(II) chain and uncoordinated hydrogen phthalate anions. The manganese(II) ions are bridged with two 1,2,4-traizoles and one chloride anion along the cationic chain, in which the weak antiferromagnetic exchange occurs between manganese(II) atoms. CCDC: 267461.
A novel one-dimensional chain manganese (II) compound Mn (trz) 2ClphthH, (trz = 1,2,4- triazole, phthH = hydrogen phthalate), 1 was synthesized and structurally characterized. It crystallizes in monoclinic system, space group It consists of a = 1.381 1 (11) nm, b = 0.815 5 (7) nm, c = 0.735 4 (6) nm, β = 94.667 (15) °, V = 0.825 5 of one dimensional cationic manganese (II) chain and uncoordinated hydrogen phthalate anions. The manganese (II) ions are bridged with two 1,2,4-traizoles and one chloride anion along the cationic chain, in which the weak antiferromagnetic exchange occurs between manganese (II) atoms. CCDC: 267461.