循环伏安法研究表明2,2′-联吡啶催化Co(Ⅱ)通过水/硝基苯界面的相转移伴有化学反应发生。水相或有机相的伴随化学反应直接影响Co(Ⅱ)与2,2′-联吡啶逐级配合物的相转移的循环伏安行为,并观察到类似于金属电极/电解质溶液界面出现的不可逆渡,不同的配合物,相转移机制不同。 Cyclic voltammetry studies show that 2,2’-dipyridyl catalyzes the phase transition of Co (II) through a water / nitrobenzene interface with chemical reactions. Concomitant chemical reactions in the aqueous or organic phase directly affect the cyclic voltammetry behavior of the phase transfer of the Co (II) and 2,2’-bipyridyl complexes, and irreversible changes similar to those observed at the metal electrode / electrolyte solution interface Ferry, different complexes, different mechanisms of phase transfer.