We report heat treatment of the photonic crystal fiber. As the temperature was increased, the transmission of the photonic crystal fiber was increased, unlike conventional single mode fiber. The transmission increase at short wavelength region was larger than long wavelength region for the various temperatures. After crystallization of the silica glass, the spectra of the photonic crystal fiber were just decreased at all wavelength regions, but, in case of the single mode fiber, the absorption in visible region around 450 nm increased with increasing temperature. As the temperature was increased, the transmission of the photonic crystal glass was increased, the transmission of the short wavelength region was larger than the long wavelength region for the various temperatures. After crystallization of the silica glass, the spectra of the photonic crystal fibers were just decreased at all wavelength regions, but, in case of the single mode fiber, the absorption in visible region around 450 nm increased with increasing temperature.