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A new nickel(II) coordination complex [Ni(2,2’-bipy)2(ClC6H4COO)(H2O)](ClO4) was synthesized by self-assembly reaction of m-chlorobenzoic acid, 2,2’-bipy and Ni(ClO4)2’6H2O. The crystal of the title compound belongs to monoclinic system, space group P21/n with a = 0.77764(14), b = 2.6572(5), c = 1.3637(2) nm, β = 96.456(3)o, V = 2.8000(9) nm3, Dc = 1.528 g/cm3, Z = 4, Mr = 644.10, μ(MoKα) = 0.937 mm-1, F(000) =1320, R = 0.0549 and wR = 0.1164. Structure analysis shows that the nickel(II) ion is coordinated with four nitrogen atoms from two bipys as well as two oxygen atoms from m-chlorobenzoic acid and water, respectively, giving a distorted octahedral coordination geometry. The cyclic voltametric behavior of the complex is also presented.
A new nickel (II) coordination complex [Ni (2,2’-bipy) 2 (ClC6H4COO) (H2O)] (ClO4) was synthesized by self-assembly reaction of m-chlorobenzoic acid, (ClO4) 2’6H2O. The crystal of the title compound belongs to monoclinic system, space group P21 / n with a = 0.77764 (14), b = 2.6572 (5), c = 1.3637 (2) nm, 3 = 0, V = 2.8000 (9) nm3, Dc = 1.528 g / cm3, Z = 4, Mr = 644.10, μ (MoKα) = 0.937 mm -1, F (000) = 1320, R = 0.0549 and wR = 0.1164. Structure analysis shows that the nickel (II) ion is coordinated with four nitrogen atoms from two bipysters as well as two oxygen atoms from m-chlorobenzoic acid and water, respectively, giving a distorted octahedral coordination geometry. The cyclic voltametric behavior of the complex is also presented.