Upconversion fluorescence spectroscopy of Er3+-doped lead oxyfluorosilicate glass

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Upconversion fluorescence emission of Er3+-doped oxyfluorosilicate glass excited at 975 mn is experimen-tally investigated. The results reveal that the intense green and red emission, and weak blue emissioncentered at 525, 543, 655, and 410 nm, respectively. A two-photon upconversion process is assigned to thegreen and red emission while a three-photon process is responsible for blue upconversion. The possibleupconversion mechanisms are discussed based on excited state absorption and energy transfer betweenexcited Er3+ ions. The intense upconversion fluorescence of Er3+-doped lead oxyfluorosilicate glass maybe a potentially useful material for developing upconversion optical devices.
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