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以功能性的钌有机螯合物Ru(phen) 2 + 3 作为亚相离子 ,花生酸在亚相表面上形成稳定的单分子膜 .π A等温线和动态弹性测量表明 ,此膜因花生酸与钌螯离子发生了静电相互作用而有更大的可压缩性 ,并在固态区发生了分子聚集 .用垂直法成功地制备了嵌有Ru(phen) 2 + 3 离子的超薄有序Y 型LB膜 .光谱实验表明 ,所得LB膜是稳定、均匀的层状三明治结构 ,在层面内Ru(phen) 2 + 3 与花生酸结合成相对稳定的分子基团并形成了J 聚体
A stable monolayer was formed on the surface of the subphase with ruthenium organic chelate Ru (phen) 2 + 3 as a subphase ion.The isotherms and dynamic elastic measurements showed that this membrane was mainly composed of arachidonic acid With the ruthenium chelating ion electrostatic interaction occurred more compressibility, and in the solid state molecular aggregation occurred.Ultra-perpendicular method was successfully prepared with embedded Ru (phen) 2 +3 ultra-thin ordered Y Type LB film.The experimental results show that the LB film is a stable, uniform layered sandwich structure in which Ru (phen) 2 + 3 is combined with arachidic acid to form a relatively stable molecular group and form a J-mer