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The manganese(II) complex [Mn(acacen){N(CN)2}]n [H2acacen=bis(acetylaceton e )ethylenediimine] has been synthesized and the structure has been determined. Th e complex forms a one-dimensional chain structure via the bidentate bridge ligan d -linking [Mn(acacen)] moiety. The magnetic property of the comp ound (75~300 K) shows the existence of an antiferromagnetic exchange interaction among paramagnetic centers along the chain. CCDC: 244940.
The manganese (II) complex [Mn (acacen) {N (CN) 2}] n [H2acacen = bis (acetylaceton e) ethylenediimine] has been synthesized and the structure has been determined. Th e complex forms a one-dimensional chain structure via the bidentate bridge ligan d -linking [Mn (acacen)] moiety. The magnetic property of the compound (75-300 K) shows the existence of an antiferromagnetic exchange interaction among paramagnetic centers along the chain. CCDC: 244940.