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超分子树枝聚合物起源于聚合物链结构的2个重要进化(树枝链和超分子),是通过建筑模块在芯、支化单元或表面的分子自组装(非共价键连接)生成的树枝聚合物,具有独特的结构特征和新颖的物理、化学等功能。超分子树枝聚合物的进一步自组织可形成液晶态或柱状体等有序结构。超分子树枝聚合物可分为氢键型、金属配位型、π-π堆叠型、离子型、拓扑型(含轮烷和索烃结构)、混合型(含2种或2种以上不同非共价键)等类型。本文综述各种类型超分子树枝聚合物的合成、结构、聚集态和应用。
Supramolecular dendrimers originate from two important evolutions (dendrimers and supramolecules) of the polymer chain structure, which are branches of the building produced by self-assembly (non-covalently linked) molecules of the building block at the core, branching unit or surface Polymer, with unique structural features and novel physical, chemical and other functions. Further self-organization of supramolecular dendrimers can form ordered structures such as liquid crystal or columnar bodies. Supramolecular dendritic polymers can be classified into hydrogen bonding type, metal coordination type, π-π stacking type, ionic type, topological type (including rotaxanes and cord-based hydrocarbon structures), mixed type (containing two or more different non- Covalent bond) and other types. This review summarizes the synthesis, structure, aggregation and application of various types of supramolecular dendrimers.