Liquid crystalline polymers containing 1,2,3-triazole units as linking groups have been synthesized from the monomers containing triad ester diazide and flexible dialkyne ester by 1,3-cycloaddition reaction and were characterized. Click reaction of azide and alkyne functionals catalyzed by Cu(I) yielded target polyesters with 1,2,3-triazole groups.The structure of the polymer was confirmed by spectral techniques.GPC analysis reveals that the polymers have moderate molecular weight with narrow distribution.Hot stage optical polarizing microscopic investigation confirms the liquid crystalline nature of the polymers with lengthy flexible spacers,while the short chain containing polymers does not show the mesomorphic properties.Differential scanning calorimetric analysis confirms the formation of mesophase in some of the polymers,and it is in accordance with the microscopic results.Thermal stabilities of the polymers were analyzed by thermogravimetric analysis. Liquid crystalline polymers containing 1,2,3-triazole units as linking groups have been synthesized from the monomers containing triad ester diazide and flexible dialkyne esters by 1,3-cycloaddition reaction and were characterized. Click reaction of azide and alkyne functionals catalyzed by Cu (I) yielded target polyesters with 1,2,3-triazole groups. The structure of the polymer was confirmed by spectral techniques. GPC analysis reveals that the polymers have moderate molecular weight with narrow distribution. Hot stage optical polarizing microscopic investigation confirms the liquid crystalline nature of the polymers with lengthy flexible spacers, while the short chain containing polymers does not show the mesomorphic properties. Differential scanning calorimetric analysis confirms the formation of mesophase in some of the polymers, and it is in accordance with the microscopic results. of the polymers were analyzed by thermogravimetric analysis.