Enhanced photocatalytic water splitting with surface defective SrTiO3 nanocrystals

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Surface reconstructed SrTiO3 nanocrystals were synthesized by a thermal treatment process in presence of NaBH4 and SrTiO3 nanocrystals.The surface reconstruction of SrTiO3 nanocrystals is attributed to the introduction of surface oxygen vacancies or Ti sites (such as Ti3+ and Ti2+) during the hydrogenation treatment process.The light absorption and the charge transfer ability of SrTiO3 nanocrystals are simultaneously enhanced due to surface oxygen vacancies or Ti sites (such as Ti3+ and Ti2+),which are beneficial to photocatalytic water splitting.Meanwhile,these defects also change the redox potential of the photocatalysts.Since there existed a synergistic effect between the three,the ratio of hydrogen to oxygen production was also regulated.
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