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从人工发酵培养的蜜环菌[Armillaria mellea(Vahl.ex Fr.)Quel.属白蘑科(Tricholometaceae)真菌]菌丝体的石油醚提取物中,经硅胶层析分离得到一新的倍半萜醇芳香酸酯类化合物,命名为蜜环菌癸素(armillaripin)。根据光谱(UV,IR,~1HNMR,~(13)CNMR和MS)分析推测其化学结构,并进一步用X-线衍射晶体解析法确证其结构和其相对构型。
A new halve was obtained from the petroleum ether extract of Armillaria mellea (Vahl.ex Fr.) Quel. of the genus Tricholometaceae mycelia artificially fermented. The sterol ester type ester compound is named armillaripin. Spectra (UV, IR, ~1HNMR, ~(13)CNMR, and MS) were used to analyze the chemical structure and its structure and relative configuration were further confirmed by X-ray diffraction crystal analysis.