NiCr–Cr3C2 metal–ceramic composite coating is commonly produced on metal substrate by laser cladding to be used as wear-resistant coating under medium- or high-temperature working conditions.The coating has high hardness, generally over three times that of the substrate.In order to make the hardness increase gradually from substrate to coating surface, the nickel-based alloy Ni45 was chosen as the transition layer and Ni Cr–Cr3C2 coating was indirectly cladded on 20Cr2Ni4 A substrate.Microstructure and composition of the coating were characterized by scanning electron microscope(SEM), energy-dispersive spectroscopy(EDS) and X-ray diffraction(XRD).Microhardness of the cross section of the coating was measured.Friction and wear behavior of Ni Cr–Cr3C2coating and substrate were investigated through sliding against the Si C ball at 20, 100 and 300 °C.The morphologies of worn surfaces were analyzed by SEM and EDS.The results show that the hardness of Ni45 transition layer is between that of the substrate and Ni Cr–Cr3C2coating, which avoids hardness jump and stress concentration of the coating.Ni Cr–Cr3C2coating contains hard phases of Cr3C2 and Cr7C3which enhance the wear resistance.With thetemperature increasing, friction coefficient and wear rate of the substrate increase significantly.Compared with the substrate, Ni Cr–Cr3C2coating has lower friction coefficient and wear rate at 100 and 300 °C, which verifies the good wear resistance of NiCr–Cr3C2 coating. NiCr-Cr3C2 metal-ceramic composite coating is commonly produced on metal substrate by laser cladding to be used as wear-resistant coating under medium- or high-temperature working conditions. The coating has high hardness, generally over three times that of the substrate. In order to make the hardness increase gradually from substrate to coating surface, the nickel-based alloy Ni45 was chosen as the transition layer and Ni Cr-Cr3C2 coating was subsequently cladded on 20Cr2Ni4 A substrate. Microstructure and composition of the coating were characterized by scanning electron microscopy (SEM), energy-dispersive spectroscopy (EDS) and X-ray diffraction (XRD). Microhardness of the cross section of the coating was measured.Friction and wear behavior of Ni Cr-Cr3C2 coating and substrate were investigated through sliding against the Si C ball at 20, 100 and 300 ° C. The morphologies of worn surfaces were analyzed by SEM and EDS. The results show that the hardness of Ni45 transition layer is betwee n that of the substrate and Ni Cr-Cr3C2 coating, which avoids hardness jump and stress concentration of the coating .Ni Cr-Cr3C2coating contains hard phases of Cr3C2 and Cr7C3which enhance the wear resistance .With thetemperature increasing, friction coefficient and wear rate of the substrate increase significantly. Compared with the substrate, Ni Cr-Cr3C2coating has lower friction coefficient and wear rate at 100 and 300 ° C, which verifies the good wear resistance of NiCr-Cr3C2 coating.