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A ring-opening process of 4-imino-l,3-thiazetidin-2-ones with NH_2OH·HC1 was described for the first time.Two different scaffolds of imidodicarbonic diamide were obtained selectively in good yields in the presence of organic base.The obtained imidodicarbonic diamides were demonstrated by X-ray diffraction analysis.
A ring-opening process of 4-imino-l, 3-thiazetidin-2-ones with NH 2 OH · HC1 was described for the first time. Two different scaffolds of imidodicarbonic diamide were obtained in good results in the presence of organic base. obtained imidodicarbonic diamides were demonstrated by X-ray diffraction analysis.