金属簇合物因其独特的结构和成键而引人注目,鉴于文献上对铑簇合物的结构、成键、反应和催化性能存在不同看法,本文的两个铑簇合物的简正振动分析以及另文的铑系列簇合物的电子结构计算和催化性能研究,为进一步认识上述问题提供了有意义的结果。简正振动分析 Rh_2(CO)_4(μ-Cl)_2(1)参照文献[8]合成,其红外光谱是用石蜡油糊涂KBr(中红外区)和 Due to their unique structure and bonding, metal clusters attract people’s attention. In view of the literature on the structure of rhodium clusters, bonding, reaction and catalytic properties of different views, two rhodium clusters in this article, Vibration analysis as well as the electronic structure calculations and catalytic properties of rhodium clusters have also provided meaningful results to further understand the above problems. The simple vibration analysis Rh_2 (CO) _4 (μ-Cl) _2 (1) was synthesized by reference [8]