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5. Kinetics and mechanism studies on scandium calix[6]arene complex initiating ring-opening polymerizat

Kinetics and mechanism studies on scandium calix[6]arene complex initiating ring-opening polymerizat

来源 :中国科学：化学英文版 | 被引量 : 0次 | 上传用户：lanses

【摘 要】

：

Scandium p-tert-butylcalix[6]arene complex has been synthesized from scandium isopropoxide and p-tert-butylcalix[6]arene and used as a single component initiato

【作 者】

：

GOU PengFei ZHU WeiPu SHEN Zhi 

【机 构】

：

KeyLaboratoryofMacromoleculeSynthesisandFunctionalization

【出 处】

：

中国科学：化学英文版

【发表日期】

：

2007年5期

【关键词】

：

RING-OPENING polymerization SCANDIUM CALIXARENE complex 2 2-dimethyltrimethyle 

【基金项目】

：

Supported by the National Natural Science Foundation of China (Grant no. 20434020), the Special Fund for Major State Basic Research Project (Grant No. G2005CB623802) and the Committee of Science and T

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Scandium p-tert-butylcalix[6]arene complex has been synthesized from scandium isopropoxide and p-tert-butylcalix[6]arene and used as a single component initiator for the first time. The polymerization of 2,2-dimethyltrimethylene carbonate (DTC) using this

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