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根据化学反应热动力学的基本原理 ,推导了连续一级反应的积分和微分热动力学方程 ,建立了连续一级反应热动力学时间参量法的数学模型 ,通过对己二酸二乙酯和邻苯二甲酸二乙酯皂化反应的热动力学研究 ,验证了连续一级反应时间参量法的正确性
According to the basic principle of thermodynamics of chemical reaction, the integral and differential thermodynamics equations of continuous first order reaction are deduced. The mathematical model of the thermokinetic time parameter method for continuous first order reaction is established. The thermodynamic study on the saponification of diethyl phthalate proved the correctness of the continuous first-order reaction time parameter method