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文献[1—3]曾报导过应用等离子体聚合方法制备有机聚合物薄膜,为掌握等离子体聚合物的性能,进而扩展其用途,对其结构进行研究具有一定的意义。Kobayashi等研究了用内部电极等离子体装置制备的聚乙烯的结构,并指出其为交联结构,他们用同样装置研究了单体流量对丙烯聚合膜淀积速率的影响。我们用较简单的外部电容耦合式聚合装置,研究了在辉光区中乙烯和丙烯的聚合规律,并应用元素分析、红外光谱和X射线衍射法研究了聚合物的结构。
The literature [1-3] reported that the preparation of organic polymer films by plasma polymerization has some significance for understanding the properties of plasma polymers and further expanding their applications. Kobayashi et al. Studied the structure of polyethylene prepared with an internal electrode plasma device and pointed out that it was a cross-linked structure. They used the same apparatus to study the influence of the monomer flow on the deposition rate of the propylene polymerization film. We used a simpler external capacitive coupling polymerization device to study the law of polymerization of ethylene and propylene in the glow zone and studied the structure of the polymer by elemental analysis, infrared spectroscopy and X-ray diffraction.