【摘 要】
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The reactions of [(η5-C5Me5)Mo(StBu)3] with equimolar FeBr3 in THF afforded a neutral tetranuclear cluster [(η5-C5Me5)2Mo2Fe2S4Br2] 1. The structure of 1 was
【机 构】
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Department of Chemistry and Chemical Engineering
论文部分内容阅读
The reactions of [(η5-C5Me5)Mo(StBu)3] with equimolar FeBr3 in THF afforded a neutral tetranuclear cluster [(η5-C5Me5)2Mo2Fe2S4Br2] 1. The structure of 1 was determined by single-crystal X-ray diffraction analysis. 1 crystallizes in the monoclinic space group P21/n (No. 14) with a = 9.691(2), b = 15.204(2), c = 18.850(2) A, β = 96.44(1)°, V = 2759.8(7) A3, Z = 4, Mr = 862.08, Dc = 2.075 g/cm3, F(000) = 1680, μ (MoKα) = 51.31 cm-1 and T = 296.2 K. With the use of 3667 observed reflections (I > 3.0σ(I)), the structure was refined to R = 0.041 and Rw = 0.051. 1 is composed of a distorted Mo2Fe2S4 cubane core with two Br atoms and two η5-C5Me5 groups coordinating at the Fe and Mo sites, respectively. The lengths of Mo-Mo and Fe-Fe bonds are 2.826 and 2.773 A, respectively the mean length of Mo-Fe bond is 2.751 A.
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