The new technology of continuous casting by heated mold was used to produce dtirectional solidification ZA alloy lines to eliminate the inter defects of these lines and increase their mechanical properties. The results are as follows: (1) The microstructure of the ZA alloy lines is the parallel directional dendritic columnar crystal. Every dendritic crystal of eutectic alloy ZA5 was composed of many layer eutectic β and η phases. The microstructure of hypereutectic ZA alloys is primary dendritic crystal and interdendritic eutectic structure. The primary phase of ZA8 and ZA12 isβ,among them, but the primary phase of ZA22 and ZA27 is α. (2) Through the test to the as-cast ZA alloy lines made in continuous casting by heated mold, it is found that the tensile strength and hardness increase greatly, but the elongation decreases. With the increase of aluminum amount from ZA 5 to ZA 12, ZA22 and ZA27, the tensile strength increases gradually. ZA27 has the best comprehensive mechanical properties in these four kinds of ZA alloys. (3) Heat treatment can decrease the dendritic segregation and improve the elongation of ZA alloy, but make their strength decrease slightly.