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The morphology and crystallography of phases in the Cu-0.12% Zr alloy were investigated by scanning electron microscope(SEM), transmission electron microscope(TEM), and high-resolution transmission electron microscope(HRTEM). The results show that the as-cast microstructure of Cu–Zr alloy is mainly Cu matrix and eutectic structure which consist of Cu and Cu5Zr phases with a fine lamellar structure. The disk-shaped and plateliked Cu5Zr phases with fcc structure are found in the matrix, in which habit plane is parallel to {111}a plane of the matrix.Between the copper matrix and Cu5Zr phase,there exists an orientation relationship of [112]a|| [011]Cu5Zr;(111)a||(111)Cu5Zr. The space structure model of Cu5Zr phase can be established.
The morphology and crystallography of phases in the Cu-0.12% Zr alloy were investigated by scanning electron microscope (SEM), transmission electron microscope (TEM), and high-resolution transmission electron microscope (HRTEM). The results show that the as-cast microstructure of Cu-Zr alloy is mainly Cu matrix and eutectic structure which consist of Cu and Cu5Zr phases with a fine lamellar structure. The disk-shaped and plateliked Cu5Zr phases with fcc structure are found in the matrix, in which habit plane is parallel to {111} a plane of the matrix.Between the copper matrix and Cu5Zr phase, there exists an orientation relationship of [112] a || [011] Cu5Zr; (111) a || (111) Cu5Zr. The space structure model of Cu5Zr phase can be established.