论文部分内容阅读
利用式E_Ⅱ(min)=E_B(K)-E_i(L_(23)~+L_(23)~+)可以从OKL_(23)L_(23)价态型俄歇跃迁能量求出氧的双电离能,它与杂多酸的Bronsted质子酸有一定的对应关系。本文利用铝靶的轫致辐射诱导MoL_3M_(45)M_(45)和PKL_(23)L_(23)俄歇跃迁,实现了在一个阳极和同一次实验情况下,既测得Mo、P特征的电光电子峰,又记录了高动能的俄歇峰。Mo、P的俄歇谱可表明杂原子与杂多配位原子的关系。
The double ionization of oxygen can be obtained from the Auger transition energy of the OKL_ (23) L_ (23) state by the formula E_Ⅱmin = E_B K --E_i L_23 + L_23 + Can, it and the heteropoly acid Bronsted proton acid has a certain correspondence. In this paper, AlL targets were irradiated by Al target to induce the MoL_3M_ (45) M_ (45) and PKL_ (23) L_ (23) Auger transitions to achieve both the anodic and the same experimental conditions, Electro-optic peak, and recorded a high kinetic energy Auger peak. Auger spectra of Mo and P indicate the relationship between heteroatoms and heteropoly-coordinated atoms.