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Two oxo-vanadium(IV) complexes, [VO(C2O4)(2,2′-bipy)(H2O)]·C2H5OH(1) and VO(C2O4)(phen)(H2O) (2), where 2,2′-bipy=2,2′-bipyridyl, phen=1,10-phenanthroline, were synthesized as potential functional models of vanadium haloperoxidases(VHPOs) in mixed so