论文部分内容阅读
本文对10种苯并氧化呋咱及其衍生物的XPS谱做了系统的分析。发现E_b~*值与分子内CT作用间存在良好的相关关系,并获得了CNDO/2理论计算的有力支持。此外,XPS结合能的分析可为了解氧化呋咱电子结构提供重要信息。
In this paper, XPS spectra of 10 benzofuranoxazines and their derivatives were systematically analyzed. It was found that there was a good correlation between the E_b ~ * value and the intramolecular CT effect and the powerful support of the theoretical calculation of CNDO / 2. In addition, the analysis of XPS binding energy provides important information for understanding the electronic structure of furazan.