【摘 要】
：
An energetic salt, sodium nitroformate (NaNF), was synthesized and characterized by elemental analysis, IR and UV spectra, and its crystal structure was first determined by single crystal X-ray diffraction. The structure exhibits two types ofπ-πstacking i
【机 构】
：
College of Materials Science and Engineering, Chongqing University, Chongqing 400030, China;State Ke
【出 处】
：
武汉理工大学学报（材料科学版）（英文版）
论文部分内容阅读
An energetic salt, sodium nitroformate (NaNF), was synthesized and characterized by elemental analysis, IR and UV spectra, and its crystal structure was first determined by single crystal X-ray diffraction. The structure exhibits two types ofπ-πstacking interactions between the nitroformate anions, i e, the parallel-displaced and T-shaped configurations. Furthermore, the thermal decomposition mechanism was investigated by DSC, TG-DTG and FTIR techniques. The kinetic parameters of the thermal decomposition were also calculated by using Kissinger’s and Ozawa-Doyle’s methods. The results show that NaNF has a good thermal stability, which is attributed to theπ-πstacking interactions.
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