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合成含二茂铁核高分子是近年来元素有机高分子领域中受到人们注意的和感到兴趣的课题。自1955年以来,Arimoto首先报导了乙烯基二茂铁的合成和它的聚合;其后有人报导主链中合二茂铁核的高分子,并研究它们异常的磁性;还有人报导过将二茂铁核引入硅有机高分手中得到具有耐高温和耐辐射的液体材料。虽然有关这方面工作的文献为数不多,它的实际用途尚未能肯定,但把二茂铁的特殊結构引进高分子中,估計有可能得到具有优越性能的高分子材料。 为此,我们合成了一些合烯基二茂铁的单体,通过聚合得到侧链合二茂铁核的高分子化合物,并作了一些基本性能的初步测定,本文拟着重报导这些单体的合成以及它们初步
The synthesis of ferrocene-containing macromolecules is a subject that has drawn much attention and interest in the field of elemental organic polymers in recent years. Arimoto first reported the synthesis of vinylferrocene and its polymerization since 1955; later it was reported that the ferrocene core polymers in the main chain, and their abnormal magnetic properties; it was also reported that the two Ferrocene into the organic silicon hand score to get a high temperature and radiation resistant liquid material. Although there are only a few literatures about its work in this field and its practical use has not yet been confirmed, it is estimated that the introduction of the special structure of ferrocene into macromolecules will make it possible to obtain polymer materials with superior properties. To this end, we have synthesized a number of alkenyl alkenyl ferrocene monomer obtained by polymerization of side-ferrocene polymer compounds, and made some preliminary determination of the basic properties, this article will focus on the reports of these monomers Synthesis and their preliminary