【摘 要】
：
A neutral dinuclear compound Cu2[(O=PPh2)2N]2(μ-O2PPh2)2 has been unexpec- tedly prepared from the reaction of [Cu2(dppa)2(MeCN)4](ClO4)2 (dppa = bis(diphenylp
【机 构】
：
State Key Laboratory of Structural Chemistry
【基金项目】
：
国家自然科学基金;the State Key Laboratory of Structural Chemistry, the National Science and Technology of China;the NaturalScience Foundation of CAS and Fujian Province
论文部分内容阅读
A neutral dinuclear compound Cu2[(O=PPh2)2N]2(μ-O2PPh2)2 has been unexpec- tedly prepared from the reaction of [Cu2(dppa)2(MeCN)4](ClO4)2 (dppa = bis(diphenylphosphino)- amine) and Sn(edt)2 (edt = ethane-1,2-dithiolate) in dichloromethane in air. ESR spectrum shows that the original Cu+ ion has been oxidized. The crystal structure determined by an X-ray single diffrac- tometer displays that the concurrence of the redox and hydrolysis of the origin ligand dppa is taken with the formation of two new ligands. The complex crystallizes in triclinic, space group P with a = 9.4269(13), b = 10.7522(13), c = 16.787(2)(A), ( = 92.042(5), β = 104.591(7), γ = 96.167(6)°, V = 1633.6(4)(A)3, C72H60 Cu2N2O8P6, Mr = 1394.12, Z = 1, Dc = 1.419 g/cm3, F(000) = 718, μ = 0.856 mm-1, the final R = 0.0530 and wR = 0.1096 for 4210 observed reflections with I > 2σ(I).
其他文献
To investigate the pharmacokinetics of felodipine in the plasma of healthy Chinese volunteers, 30 healthy volunteers received a single oral dose of 5 mg of exte
A compound (NH3CH2CH2NH3)HgSnS4 with a column structure was synthesized solvothermally and characterized by X-ray single-crystal diffraction. This compound crys
The authors consider the moderate deviations of hydrodynamic limit for Ginzburg-Landau models. The moderate deviation principle of hydrodynamic limit for a spec
In order to study the effect of minerals on biomass pyrolysis, experiments on pyrolysis of corn straw with different pretreatment methods were performed by usin
Supersaturated design is essentially a fractional factorial design in which the number of potential effects is greater than the number of runs. In this article,
The effect of the waving bed on the surface wave was investigated. The wave equation was reduced from the potential flow theory with the perturbation technique,
Thin film morphology of a symmetric semicrystalline oxyethylene/oxybutylene diblock copolymer (E76B38) on silicon was investigated by tapping mode atomic force
Surface modification by physical adsorption of a series of non-ionic surfactants including Tween 20, Tween 40,Tween 60, Tween 80 and Tween 85, was accomplished
The nonlinear hydrodynamic interaction between a floating elliptic cylinder and a vibrating circular cylinder immersed in an infinite fluid was investigated. By
在以生物质气体为燃料的固体氧化物燃料电池体系中,通过热力学平衡分析编程计算出700～1200 K时气体中各物种例如H2、CO、CO2和CH4的平衡组成,从而得到以氧化钇稳定氧化锆(YSZ)