Joule-heated carbonized melamine sponge for high-speed absorption of viscous oil spills

来源 :纳米研究(英文版) | 被引量 : 0次 | 上传用户:yujian136
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
Introducing heating function to oil sorbents opens up a new pathway to the fast cleanup of viscous crude oil spills in situ.The oil sorption speed increases with the rise of the temperature,thus oil sorbents with high heating temperature are desirable.Besides,the oil sorbents also need to be produced environment-friendly.Here we present carbonized melamine-formaldehyde sponges(CMSs) that exhibited superior heating performance and the CMSs could be massively fabricated through a non-polluting pyrolysis process.The conductive CMSs could be heated over 300 ℃ with a low applied voltage of 6.9 V and keep above 250 ℃ for 30 min in the air without obvious damage.Such high heating performance enabled heating up the oil spills with a high rate of 2.65 ℃·s-1 and 14% improvement of oil sorption coefficient compared with the state-of-the-art value.We demonstrated that one joule-heated CMS could continuously and selectively collect viscous oil spills (9,010 mPa.s) 690 times its own weight in one hour.The CMSs will be a highly competitive sorbent material for the fast remediation of future crude oil spills.
其他文献
Rational design of earth-abundant transition metal oxides catalysts is highly desirable for developing sustainable chemical processes.Herein,we demonstrate a prospective interstitial nitrogen engineering for fabricating oxygen vacancies (OVs)-rich nitroge
Here,we report a strategy to deliver drug nanoparticles into cells with nucleus-targeting ability under a spatiotemporal control.The nanoparticles were constructed through self-assembly of photoresponsive prodrugs and free drugs.By incorporating a nucleus
Developing carbon-based electrocatalysts with excellent N2 adsorption and activation capability holds the key to achieve highly efficient nitrogen reduction reaction (NRR) for reaching its practical application.Here,we report a highly active electrocataly
Wearable biopotential sensing devices are essential to long-term and real-time monitoring of human health.Non-contact,capacitive sensing electrodes prevent potential skin irritations,and are thus beneficial for long-term monitoring.Existing capacitive ele
Spirothiopyran (STP) is particularly attractive when used as a mechanophore to endow polymers with both damage-signaling and self-reinforcing capacity.It is,however,not clear the actual force required to induce the cycloreversion of STP into ring-opened t
Design of metal-free photocatalysts with customized chemical structure and nano-architecture is promising for photocatalytic hydrogen peroxide (H2O2) production.Herein,for the first time,mesoporous resorcinol-formaldehyde (MRF) nanobowls with optimized be
Fluorinated porous organic networks (F-PONs) have demonstrated unique properties and applications,but approaches capable of affording F-PONs with high fluorine content and robust nanoporous architecture under metal-free and easy handling conditions are st
Cationic azole-based metal-organic frameworks (MOFs) with remarkable stability and unique pore environment have aroused great research interests.Meanwhile,flexible MOFs which can undergo pore-structure changes upon exposure to external stimuli are ideal m
It is challenging to develop an in vitro catalytic system to conduct natural surface-confined enzymatic reactions in a stable,efficient,and spatially defined manner.Here,we report that an artificial catalyst,which composes of trypsin and a calcium ion exc
Copper-hydrides have been intensively studied for a long time due to their utilization in a variety of technologically important chemical transformations.Nevertheless,poor stability of the species severely hinders its isolation,storage and operation,which