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The effect of self absorption on the ratio of excimer to monochromophore emission intensities, I_e/I_m, has beenexplored by experimentally changing the solution layer thickness of the emission light path traversed in the solution in theright-angle geometry. The result shows that data obtained by front-face geometry are better than those obtained by right-angle geometry even after correction to zero solution thickness. The correction formula based on geometric optics given byTsai and Torkelson is not adequate.
The effect of self absorption on the ratio of excimer to monochromophore emission intensities, I_e / I_m, has beenexplored by experimentally changing the solution layer thickness of the emission light path traversed in the solution in theright-angle geometry. front-face geometry are better than those obtained by right-angle geometry even after correction to zero solution thickness. The correction formula based on geometric optics given by Tsai and Torkelson is not adequate.