论文部分内容阅读
采用UHF/AM1方法对 2 二甲胺基苯甲酰叠氮、2 二甲胺基 3 甲基苯甲酰叠氮和 2 二甲胺基 3 硝基苯甲酰叠氮的热分解反应进行了研究 .结果表明 ,这些反应物能沿着四条竞争的反应路径生成三种不同的产物 .这三条路径中有协同过程 ,也有分步过程 ;有吸热过程 ,也有放热过程 .不同的取代基 ,将选择不同的路径进行分解反应 .
The thermal decomposition of 2-dimethylaminobenzoyl azide, 2-dimethylamino 3-methylbenzoyl azide and 2-dimethylamino 3-nitrobenzoyl azide by UHF / AM1 The results show that these reactants can generate three different products along the four competing reaction paths.The three paths have a synergistic process, but also a step-by-step process, an endothermic process, but also an exothermic process.Different substituents , Will choose a different path for decomposition reaction.