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以Pd为催化剂,实现了二茂铁乙炔与脂肪醇的羰基化,并考察了不同结构的醇类底物对反应的影响。结果表明,在Pd Br2和Cu Br2催化体系下,以乙酸钠为碱,可以较高的产率合成一系列标题化合物。其结构经1HNMR、13CNMR和HR-MS表征。
With Pd as catalyst, the carbonylation of ferrocene acetylene and fatty alcohol was achieved. The effects of different structures of alcoholic substrates on the reaction were also investigated. The results show that a series of title compounds can be synthesized with higher yield in the presence of sodium acetate as the base under Pd Br2 and Cu Br2 catalysis. Its structure was characterized by 1HNMR, 13CNMR and HR-MS.