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C60H42O8F9S3P2Eu,Mr=1372.07 triclinic, space group Pl,a = 11.191(1), b = 12.121(2), c = 23.529(3) A,α=80.08(1),β=76.51(1),γ=70.46(1)°,V=2909.3(6)A3, Dm(flotation in CCl4/BrCH2CH2Br) = 1.566, Dx(Z=2) = 1.562 g cm-3,λ(MoKα) =0.71073 A,μ=13.16 cm-1, F(OOO)=1376, T =295 °K, final RF=0.033 for 9104 observed reflections with |Fσ|>3σ(|Fσ|).The compound is isostructural with the known neodymium(Ⅲ) complex. The metal atom in the monomeric molecule is coordinated dodecahedrally by the eight 0 atoms of the surrounding ligands with Eu-0 bond distances in the range 2.361(2)-2.457(3) A.
A = 11.191 (1), b = 12.121 (2), c = 23.529 (3) A, α = 80.08 (1), β = 76.51 (1), γ = 70.46 (1) °, V = 2909.3 (6) A3, Dm (flotation in CCl4 / BrCH2CH2Br) = 1.566, Dx (Z = 2) = 1.562 g cm -3, λ (MoKα) = 0.71073 A, μ = 13.16 cm- F (OOO) = 1376, T = 295 ° K, final RF = 0.033 for 9104 observed reflections with | Fσ |> 3σ (| Fσ |). The compound is isostructural with the known neodymium (III) complex. atom in the monomeric molecule is coordinated dodecahedrally by the eight 0 atoms of the surrounding ligands with Eu-0 bond distances in the range 2.361 (2) -2.457 (3) A.