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The assembly of 1,4-benzenedicarboxylic acid (H2bdc), 4,4?bipyridine (4,4?bipy), trimethyltin chloride and MnBr24H2O in hydrothermal conditions gave rise to a hydrogen-bonded three-dimensional complex {[Mn(4,4?bipy)4H2O](bdc)}n which has been characterized by single- crystal X-ray diffraction. The complex crystallizes in the monoclinic system, space group P2/n with a = 7.0001(2), b = 11.5540(3), c = 11.4192(1) ? = 101.754(2)? V = 904.21(4) 3, Z = 2, C18H20MnN2O8, Mr = 447.30, Dc = 1.643 g/cm3, F(000) = 462 and m(MoK? = 0.783 mm-1. The final R and wR are 0.0499 and 0.1301, respectively for 1335 observed reflections with I ≥ 2(I). The Mn (Ⅱ) is six-coordinated in a distorted octahedral geometry. 4,4?Bipyridine in a m-bridge mode links [Mn(H2O)4]2+ into a linear cation chain. bdc acts as a counter anion and links the linear chains into a three-dimensional structure through hydrogen bonds.
The assembly of 1,4-benzenedicarboxylic acid (H2bdc), 4,4? Bipyridine (4,4? Bipy), trimethyltin chloride and MnBr24H2O in hydrothermal conditions gave rise to a hydrogen-bonded three- 4? Bipy) 4H2O] (bdc)} n which has been characterized by single-crystal X-ray diffraction. The complex crystallizes in the monoclinic system, space group P2 / n with a = 7.0001 (2), b = 11.5540 , C = 11.4192 (1)? = 101.754 (2)? V = 904.21 (4) 3, Z = 2, C18H20MnN2O8, Mr = 447.30, Dc = 1.643 g / cm3, F (000) = 462 and m ? = 0.783 mm-1. The final R and wR are 0.0499 and 0.1301, respectively for 1335 observed reflections with I ≥ 2 (I). The Mn (II) is six-coordinated in a distorted octahedral geometry. in a m-bridge mode links [Mn (H2O) 4] 2+ into a linear cation chain. bdc acts as a counter anion and links the linear chains into a three-dimensional structure through hydrogen bonds.