“金属有机化合物的合成及在高选择性反应中的应用“是国家自然科学基金“七五”重大项目,由国家教委和中科院所属5个单位承担,已于1993年4月底完成并通过评议验收,项目总评为优秀。“七五”期间获国家自然科学奖二等奖1项,部委级奖11次,发表论文495篇,专著16部,国际会上作邀请报告17次,共培养研究生150名。本文介绍该重大项目所取得的主要成果和研究进展。 “Synthesis of metal-organic compounds and their application in high-selectivity reaction” is a major project of the “Seventh Five-Year Plan” by the National Natural Science Foundation of China, which is undertaken by the State Education Commission and the Chinese Academy of Sciences. It was completed by the end of April 1993 and passed the appraisal and acceptance , The total project rating is excellent. During the “Seventh Five-Year Plan” period, it won 1 second prize of National Natural Science Award, 11 ministerial-level awards, 495 papers, 16 monographs and 17 invitations at international conferences, and a total of 150 graduate students were trained. This article introduces the major achievements and research progress of this major project.