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Two novel interpenetrating diamond frameworks,namely [Cd(mal)(bix)]n(1) and {[Zn(sub)(bib)]n·H2O}n(2)(H2mal=maleic acid,H2 sub=suberic acid,bix=1,4-bis(imidazol-1-ylmethyl)-benzene,bib=1,4-bis(N-imidazolyl)butane) were hydrothermally synthesized and characterized by elemental analysis,infrared spectra(IR),and single-crystal X-ray diffraction.Single-crystal X-ray diffraction analysis reveals that compound 1 crystallizes in the orthorhombic system with space group Pnma and features a 3-fold interpenetrating diamond framework.Compound 2 exhibits a 4-fold interpenetrating diamond network.The luminescent properties of these two compounds have also been investigated in detail.
Two novel interpenetrating diamond frameworks, namely [Cd (mal) (bix)] n (1) and {[Zn (sub) (bib)] n · H2O} n (H2mal = maleic acid, H2 sub = suberic acid , bix = 1,4-bis (imidazol-1-ylmethyl) -benzene, bib = 1,4-bis (N-imidazolyl) butane were hydrothermally synthesized and characterized by elemental analysis, infrared spectra (IR), and single- crystal X-ray diffraction.Single-crystal X-ray diffraction analysis reveals that compound 1 crystallizes in the orthorhombic system with space group Pnma and features a 3-fold interpenetrating diamond framework. Compound 2 exhibits a 4-fold interpenetrating diamond network.The luminescent properties of these two compounds have also been investigated in detail.