The effect of different tempering temperatures on the microstructure and mechanical properties of airquenched high boron white cast iron was studied.The results indicate that the high boron white cast iron comprises dendritic matrix and inter-dendritic M 2 B boride;and the matrix comprises martensite and pearlite.After quenching in the air,the matrix is changed into lath martensite;but only 1-μm-size second phase exists in the matrix.After tempering,another second phase of several tens of nanometers is found in the matrix,and the size and quantity increase with an increase in tempering temperature.The two kinds of second precipitation phase with different sizes in the matrix have the same chemical formula,but their forming stages are different.The precipitation phase with larger size forms during the austenitizing process,while the precipitation phase with smaller size forms during the tempering process.When tempered at different temperatures after quenching,the hardness decreases with an increase in the tempering temperature,but it increases a little at 450 ℃ due to the precipitation strengthening effect of the second phase,and it decreases greatly due to the martensite decomposition above 450 ℃.The impact toughness increases a little when tempered below 300 ℃,but it then decreases continuously owing to the increase in size and quantity of the secondary precipitate above 300 ℃.Considered comprehensively,the optimum tempering temperature is suggested at 300 ℃ to obtain a good combination of hardness and toughness. The effect of different tempering temperatures on the microstructure and mechanical properties of airquenched high boron white cast iron was studied. The results indicate that the high boron white cast iron comprises dendritic matrix and inter-dendritic M2B boride; and the matrix comprises martensite and pearlite. After quenching in the air, the matrix is ​​changed into lath martensite; but only 1-μm-size second phase exists in the matrix. After tempering, another second phase of several tens of nanometers is found in the matrix, and the size and quantity increase with an increase in tempering temperature. two kinds of second precipitation phase with different sizes in the matrix have the same chemical formula, but their forming stages are different. precipitation part with larger size forms during the austenitizing process, while the precipitation phase with smaller size forms during the tempering process .When tempered at different temperatures after quenching, the hardness decreases wit h an increase in the tempering temperature, but it it increases a little at 450 ° C. due to the precipitation strengthening effect of the second phase, and it decreases due due to the martensite decomposition above 450 ° C. The impact toughness increases a little when tempered below 300 ℃, but it then decreases continuously due to the increase in size and quantity of the secondary precipitate above 300 ℃ .Considered comprehensively, the optimum tempering temperature is suggested at 300 ℃ to obtain a good combination of hardness and toughness.