【摘 要】
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Free radical fluoroalkylation of terminal alkenes and alkynes with iododifluoromethanesulfonamides has been successfully achieved.It was found that both the cat
【出 处】
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Science China(Chemistry)
论文部分内容阅读
Free radical fluoroalkylation of terminal alkenes and alkynes with iododifluoromethanesulfonamides has been successfully achieved.It was found that both the catalytic amount of sodium dithionite (Na2S2O4) and the stoichiometric amount of triethylborane (Et3B)/air can efficiently initiate the current free-radical atom transfer reaction.
Free radical fluoroalkylation of terminal alkenes and alkynes with iododifluoromethanesulfonamides has been successfully achieved. It was found that both of the catalytic amounts of sodium dithionite (Na2S2O4) and the stoichiometric amount of triethylborane (Et3B) / air cans of the current free-radical atom transfer reaction.
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