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A novel photocatalyst of La MnO3/graphene thin films with the perovskite-type was synthesized by sol-gel process assisted with spin-coating methods on glass substrates.The prepared samples were characterized by scanning electron microscopy(SEM), transmission electron microscopy(TEM), X-ray diffraction(XRD), Brumauer-Emmett-Teller(BET) surface area analyzer, X-ray photoelectron spectroscopy(XPS) and UV-vis diffuse reflectance spectroscopy.Results showed that after the introduction of graphene, the perovskite structure was unchanged and the size of La MnO3 particles was about 22 nm, which uniformed growth in graphene sheet.Determination of contact angle indicated that the contact angle of glass substrate decreased and the hydrophilicity improved after treating with H2SO4 and APTES.The UV-Vis photocatalytic activity of the photocatalysts was evaluated by the degradation of diamine green B.La MnO3/graphene thin films had better photocatalytic ability than La MnO3 and Ti O2 films.The obtained k was 0.5627 and 0.3441 h–1 corresponding to La MnO3/graphene films and Ti O2 films, respectively.
A novel photocatalyst of La MnO3 / graphene thin films with the perovskite-type was synthesized by sol-gel process assisted with spin-coating methods on glass substrates. The prepared samples were characterized by scanning electron microscopy (SEM), transmission electron microscopy (XRD), Brumauer-Emmett-Teller (BET) surface area analyzer, X-ray photoelectron spectroscopy (XPS) and UV-vis diffuse reflectance spectroscopy. Results showed that after the introduction of graphene, the perovskite structure was unchanged and the size of LaMnO3 particles was about 22 nm, which uniformed growth in graphene sheet. Determination of contact angle indicated that the contact angle of glass substrate decreased and the hydrophilicity improved after treating with H2SO4 and APTES. The UV-Vis photocatalytic activity of the photocatalysts was evaluated by the degradation of diamine green B. LaMnO3 / graphene thin films had better photocatalytic ability than LaMnO3 and Ti O2 films. The available ed k was 0.5627 and 0.3441 h-1 corresponding to La MnO3 / graphene films and Ti O2 films, respectively.