Preparation, characterization and salt-resistance of a coal based super absorbent composite

来源 :Mining Science and Technology | 被引量 : 0次 | 上传用户:chrisfei
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
Potassium humate was extracted from brown coal. A novel super absorbent composite, poly (acrylic acid-co-acryla-mide)/potassium humate (PAA-AM/KHA), was prepared by graft polymerization of acrylic acid, acrylamide and coal based potas-sium humate using N, N’-methylenebisacrylamide as a crosslinker and potassium peroxydisulfate as an initiator. The effects of reaction temperature, degree of neutralization of the poly (acrylic acid) and the amounts of crosslinker, initiator and potassium hu-mate were investigated. Salt resistance tests were also carried out. The composite prepared under optimal conditions had a potas-sium humate content of 10% and exhibited a water absorption of 770 g/g in distilled water, and 349, 286 and 41 g/g in 0.5 mol/L KCl, MgCl2 and AlCl3 solutions respectively. The results indicate that the salt resistance of PAA-AM/KHA was superior to that of poly (acrylic acid-co-acrylamide) because of the collaborative effect of functional groups of the coal based potassium humate. The PAA-AM/KHA micro powder was characterized by IR spectroscopy and the micrographic surface was characterized by scanning electron microscopy. Introduction of potassium humate into the poly (acrylic acid-co-acrylamide) structure creates a composite more suitable for use as a water-managing material in the renewal of arid and desert environments. The salt resisting property of the composite is improved, production costs are reduced and the growth stimulant effect is still present. A novel super absorbent composite, poly (acrylic acid-co-acryla-mide) / potassium humate (PAA-AM / KHA), was prepared by graft polymerization of acrylic acid, acrylamide and coal based potas -sium humate using N, N’-methylenebisacrylamide as a crosslinker and potassium peroxydisulfate as an initiator. The effects of reaction temperature, degree of neutralization of the poly (acrylic acid) and the amounts of crosslinker, initiator and potassium hu-mate were investigated The composite prepared under optimal conditions had a potas-sium humate content of 10% and exhibited a water absorption of 770 g / g in distilled water, and 349, 286 and 41 g / g in 0.5 mol / L KCl, MgCl2 and AlCl3 solutions respectively. The results indicate that the salt resistance of PAA-AM / KHA was superior to that of poly (acrylic acid-co-acrylamide) because of collaborative effect of functional groups of the coal based potassium humate. The PAA-AM / KHA micro powder was characterized by IR spectroscopy and the micrographic surface was characterized by scanning electron microscopy. Introduction of potassium humate into the poly (acrylic acid-co-acrylamide) structure creates a composite more suitable for use as a water-managing material in the renewal of arid and desert environments. The salt resisting property of the composite is improved, production costs are reduced and the growth stimulant effect is still present.
其他文献
请下载后查看,本文暂不支持在线获取查看简介。 Please download to view, this article does not support online access to view profile.
活动目标:    1.适应新班级的学习环境。  2.引发学生对班集体的热爱。  活动过程:  教师:新的学期开始了。因为有“缘”让我们大家聚到了一起,聚到了三班这个大家庭,为了让我们的大“家”更加温暖,为了让我们每一个人每天都能在这个大“家”中快乐健康地成长,我们必须紧密团结在一起,为我们的家贡献自己的一份力量。    一、心理直播  教师:同学们一走进教室,有什么感觉?与原来的班级相比觉得怎么样
输了,为扳回老本,再赌,结果又输,直至输到倾家荡产,一无所有。这是赌徒的宿命。原郴州市住房公积金管理中心主任李树彬几年间频频将百姓的“安居钱”乾坤大挪移,化为赌资到境
我家门外的墙角下有一窝蚂蚁。它们长得可真有意思:头和屁股大大的,腰却很细,身子两边各有三条腿,头上有一对大“夹子”(那是它们的嘴),此外,它们还有一对触角。它们对伙伴很
四、研究工作的独立性国外大多数智囊机构一般在组织上不隶属于政府或企事业也不受其约束与控制。选择或承担的项目,采用的研究方法和手段,不需要什么部门、机构的批准。这
在全面推进素质教育的形势下,发展学生智力的同时加强学生能力的培养是至关重要的。本文就如何在初中物理教学中培养学生能力谈谈笔者的看法:  一、使学生认识到培养能力的重要性  1.培养能力是科学知识发展的需要。现在的科学技术发展越来越快了,知识的总量急剧增加,特别是现在的电脑应用技术更是日新月异,显然学校教育无论如何也跟不上知识更新的步伐。为解决这一问题,单纯传授知识已不能适应科学知识发展的需要,所以
论语一则子曰:“知之为知之,不知为不知,是知也。”解释孔子说:“知道的就是知道,不知道的就是不知道,这才是真正有智慧。” The Analects of Confucius said: “Knowing is
一、有效活动≠热闹活动现象:在一节三年级的新授课中,教学内容是通过复习几个动物的名称来教学句型:“This is a/an…”教学中教师先出示了一些动物的图片,复习了生词,接着
“翠微亭”位于杭州灵隐风景区飞来峰北坡半山腰,与灵隐寺宝刹中轴线主体建筑群隔冷泉池相望。据潜说友(1216-1277)《咸淳临安志》卷二三记:“绍兴十三年(1143),韩蕲王世忠于
2008年4月,我到锦州参加该市举办的古玩文化节。在一位辽西泉友处购得一枚极象尖首刀币,又具青铜刀削特征的实物,我称其为“原始尖首刀”,据出售者讲,该刀近年出于辽宁西部与河北交界的山区,但具体情况不详。细观此刀为北方生坑品,通体锈色精美,背面泛银白色沁光。从刀柄上一小砍口处,可见铜质极精,通体无文字,总长193mm,重46.9g。  说其极象尖首刀,一是整体型制与燕国尖首刀币极为相似,无论形状、比