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The keeper and cast dowel–coping, as a primary component for a magnetic attachment, is easily subjected to corrosion in a wet environment, such as the oral cavity, which contains electrolyte-rich saliva, complex micro?ora and chewing behaviour and so on. The objective of this in vitro study was to examine the corrosion resistance of a dowel and coping-keeper complex fabricated by ?nish keeper and three alloys(cobalt–chromium, Co Cr; silver–palladium–gold, Pd Au; gold–platinum, Au Pt) using a laserwelding process and a casting technique. The surface morphology characteristics and microstructures of the samples were examined by means of metallographic microscope and scanning electron microscope(SEM). Energy-dispersive spectroscopy(EDS) with SEM provided elements analysis information for the test samples after 10% oxalic acid solution etching test. Tafel polarization curve recordings demonstrated parameter values indicating corrosion of the samples when subjected to electrochemical testing. This study has suggested that massive oxides are attached to the surface of the Co Cr–keeper complex but not to the Au Pt–keeper complex. Only the keeper area of cast Co Cr–keeper complex displayed obvious intergranular corrosion and changes in the Fe and Co elements. Both cast and laser-welded Au Pt–keeper complexes had the highest free corrosion potential, followed by the Pd Au–keeper complex. We concluded that although the corrosion resistance of the Co Cr–keeper complex was worst, the keeper surface passive ?lm was actually preserved to its maximum extent. The laser-welded Co Cr–and Pd Au–keeper complexes possessed superior corrosion resistance as compared with their cast specimens, but no signi?cant difference was found between the cast and laser-welded Au Pt–keeper complexes. The Fe-poor and Cr-rich band, appearing on the edge of the keeper when casting, has been proven to be a corrosion-prone area.
The keeper and cast dowel-coping, as a primary component for a magnetic attachment, is easily subjected to corrosion in a wet environment, such as the oral cavity, which contains electrolyte-rich saliva, complex micro? Ora and chewing behavior and so on . The objective of this in vitro study was to examine the corrosion resistance of a dowel and coping-keeper complex fabricated by n nish keeper and three alloys (cobalt-chromium, Co Cr; silver-palladium-gold, Pd Au; , Au Pt) using a laser welding process and a casting technique. The surface morphology characteristics and microstructures of the samples were examined by means of metallographic microscope and scanning electron microscope (SEM). Energy-dispersive spectroscopy (EDS) with SEM provided elements analysis information for the test samples after 10% oxalic acid solution etching test. Tafel polarization curve recordings demonstrated parameter value indicating corrosion of the samples when subjected to electrochemi cal testing. This study has suggested that massive oxides are attached to the surface of the Co Cr-keeper complex but not to the Au Pt-keeper complex. Only the keeper area of cast Co Cr-keeper complex displayed obvious intergranular corrosion and changes in the Fe and Co elements. Both cast and laser-welded Au Pt-keeper complexes had the highest free corrosion potential, followed by the Pd Au-keeper complex. We concluded that although the corrosion resistance of the Co Cr-keeper complex was worst, the keeper surface passive? lm was actually preserved to its maximum extent. The laser-welded Co Cr-and Pd Au-keeper complexes possessed superior corrosion resistance as compared with their cast specimens, but no signi? cant difference was found between the cast and laser-welded Au Pt-keeper complexes. The Fe-poor and Cr-rich band, appearing on the edge of the keeper when casting, has been proven to be a corrosion-prone area.