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报道了锆-钙-茜素S异多核络合物的形成及该异多核络合物极谱吸附波测定锆的最佳实验条件．用此法测定了矿石样品中的微量锆，并探讨了该极谱波的性质的电极反应机理．在单扫描示波极谱上用单纯形法和斜率比法测得该体系异多核络合物的组成比为：nZr（Ⅳ)：nCa2+:nARS=1:1:4用分光光度法测定亦得到相同的结论．
The formation of zirconium-calcium-alizarin S heteronuclear complexes and the optimum experimental conditions for the determination of zirconium with these heteronuclear complexes were described. The trace zirconium in ore samples was determined by this method and the electrode reaction mechanism of the polarographic wave was discussed. In the single-scan oscillopolarography with the simplex method and the slope ratio method to determine the system heteronuclear complex composition ratio: nZr (Ⅳ): nCa2 +: nARS = 1: 1: 4 spectrophotometric determination Get the same conclusion.