Highly-ordered, ferroelectric, Pb-doped Ba0.7Sr0.3TiO3, inverse opal thin films were fabricated using a sol-gel spin coating technique. The excellent crystal quality is evident from the SEM images and the good agreement between the theory and experiments. Highly-ordered, ferroelectric, Pb-doped Ba0.7Sr0.3TiO3, inverse opal thin films were fabricated using a sol-gel spin coating technique. The excellent crystal quality is evident from the SEM images and the good agreement between the theory and experiments.