Five Shenfu char samples were prepared from Shenfu raw coal at different temperatures (950, 1100, 1200, 1300 and 1400 ℃) using a muffle furnace. Demineralization of the char samples was performed by treating them with 10% nitric acid for 10 min in a CEM Discover microwave reactor. The gasification of the chars, and corresponding demineralized chars, in a carbon dioxide (CO2) atmosphere was conducted in a Netzsch STA 409C131F temperature-programmed thermogravimetry apparatus. The effects of charring temperature and demineralization on the gasification reactivity of chars were systematically investigated. The results show that a char formed at a lower temperature is more reactive except for demineralized char formed at 1100 ℃, which is less reactive than char formed at 1200 ℃. Demineralization decreases the char reactivities toward gasification with CO2 to a small extent.